One of my clients had this same issue. “Reset the Printer System…” in the Printer Setup Utility (it deletes all of the printer profiles, and you need to re-add them.) was no help. We ended up having the user log out of their account. From the server sudo shelling into their account and moving/renaming /Users//Library/Preferences/Microsoft/ folder. Allowed the user to log back in and start up Word (which recreates this folder). I wasn’t able to nail it down to a specific preference file, but removing the entire folder appears to have resolved the crash on print issue.
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