One trick that might help is to set the users’ home directories to “None” in Workgroup Manager, save that, then set the new home directory, then save that. Although I have never seen it documented in print, I have gotten this advice in dealings with Apple in the past. Somewhat nonsensical, but it seems to work.
You can also check on the OD Replica to make sure that the home directory record is pointing to the right place on the replica using Workgroup Manager or dscl on the command line:
dscl /LDAPv3/127.0.0.1 -read /Users/$i NFSHomeDirectory
where $i is the username in question.
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