Remember that you can apply management at the user, computer, and workgroup level. So if an AD user isn’t a member of a workgroup, they are certainly logging in to a computer, so manage at that level.
Consider setting up a Guest computer record, and applying your managed preferences there.
The Guest computer record applies to computers that are not part of a computer list or computer group; if you have computer lists or groups defined, then apply managed preferences at that level.
One of the preferences at the computer level is to allow only members of certain workgroups to log in, which would disallow the AD users (that aren’t part of an OD workgroup) from logging in.
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