The settings are in /etc/imapd.conf
configdirectory: /var/imap
partition-default: /var/spool/imap
However, you may be better off storing stuff on a RAID and simply running a script to re-zone the storage to your second server…or go direct and simply unplug the cable from the dead server and plug it into your standby machine. Apple does not support 10.3 or 10.4 mail servers with storage on Xsan volumes:
http://docs.info.apple.com/article.html?artnum=301640
Cyrus murder is also designed to separate front-end/back-end servers for this kind of fault-tolerance/load-balancing role.
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