Post fix issues with master.cf

Hey hope somone here can help me out. I reciently putrchased the postfix enabler to allow me to send out emial as if my OS X.4 Macbook was my SMTP server, however i am getting helo errors when I try to send out using firefox.

According to the guy that developed the PSE I can not relay out on any other port unless i am using a smarthost. 2 things strike me as odd:
1. Why would I need to configure my macbook as a smtp server if I had a smarthost that I could dump to on any port
2. What is the purpose of having an SMTP if you cant change the port?

Does anyone know what the proper line config is to put into the master.cf file to get it to send out on any port other then 25 with out a smarthost?

I was told that an entry like the following causes Postfix to listen on port 10025:

10025 inet n – n – – smtpd

Now my master.cf file looks like this:

#
# Postfix master process configuration file. Each logical line
# describes how a Postfix daemon program should be run.
#
# A logical line starts with non-whitespace, non-comment text.
# Empty lines and whitespace-only lines are ignored, as are comment
# lines whose first non-whitespace character is a `#’.
# A line that starts with whitespace continues a logical line.
#
# The fields that make up each line are described below. A “-” field
# value requests that a default value be used for that field.
#
# Service: any name that is valid for the specified transport type
# (the next field). With INET transports, a service is specified as
# hostort. The host part (and colon) may be omitted. Either host
# or port may be given in symbolic form or in numeric form. Examples
# for the SMTP server: localhost:smtp receives mail via the loopback
# interface only; 10025 receives mail on port 10025.
#
# Transport type: “inet” for Internet sockets, “unix” for UNIX-domain
# sockets, “fifo” for named pipes.
#
# Private: whether or not access is restricted to the mail system.
# Default is private service. Internet (inet) sockets can’t be private.
#
# Unprivileged: whether the service runs with root privileges or as
# the owner of the Postfix system (the owner name is controlled by the
# mail_owner configuration variable in the main.cf file). Only the
# pipe, virtual and local delivery daemons require privileges.
#
# Chroot: whether or not the service runs chrooted to the mail queue
# directory (pathname is controlled by the queue_directory configuration
# variable in the main.cf file). Presently, all Postfix daemons can run
# chrooted, except for the pipe, virtual and local delivery daemons.
# The proxymap server can run chrooted, but doing so defeats most of
# the purpose of having that service in the first place.
# The files in the examples/chroot-setup subdirectory describe how
# to set up a Postfix chroot environment for your type of machine.
#
# Wakeup time: automatically wake up the named service after the
# specified number of seconds. A ? at the end of the wakeup time
# field requests that wake up events be sent only to services that
# are actually being used. Specify 0 for no wakeup. Presently, only
# the pickup, queue manager and flush daemons need a wakeup timer.
#
# Note: wakeup times for pickup, qmgr and flush are set to never to
# allow for OS X desktop sleep.
#
# Max procs: the maximum number of processes that may execute this
# service simultaneously. Default is to use a globally configurable
# limit (the default_process_limit configuration parameter in main.cf).
# Specify 0 for no process count limit.
#
# Command + args: the command to be executed. The command name is
# relative to the Postfix program directory (pathname is controlled by
# the daemon_directory configuration variable). Adding one or more
# -v options turns on verbose logging for that service; adding a -D
# option enables symbolic debugging (see the debugger_command variable
# in the main.cf configuration file). See individual command man pages
# for specific command-line options, if any.
#
# General main.cf options can be overridden for specific services.
# To override one or more main.cf options, specify them as arguments
# below, preceding each option by “-o”. There must be no whitespace
# in the option itself (separate multiple values for an option by
# commas).
#
# In order to use the “uucp” message tranport below, set up entries
# in the transport table.
#
# In order to use the “cyrus” message transport below, configure it
# in main.cf as the mailbox_transport.
#
# SPECIFY ONLY PROGRAMS THAT ARE WRITTEN TO RUN AS POSTFIX DAEMONS.
# ALL DAEMONS SPECIFIED HERE MUST SPEAK A POSTFIX-INTERNAL PROTOCOL.
#
# DO NOT SHARE THE POSTFIX QUEUE BETWEEN MULTIPLE POSTFIX INSTANCES.
#
# ==========================================================================
# service type private unpriv chroot wakeup maxproc command + args
# (yes) (yes) (yes) (never) (100)
# ==========================================================================
smtp inet n – n – – smtpd
#submission inet n – n – – smtpd
# -o smtpd_etrn_restrictions=reject
#smtps inet n – n – – smtpd
# -o smtpd_tls_wrappermode=yes -o smtpd_sasl_auth_enable=yes
#submission inet n – n – – smtpd
# -o smtpd_etrn_restrictions=reject
# -o smtpd_enforce_tls=yes -o smtpd_sasl_auth_enable=yes
#628 inet n – n – – qmqpd
pickup fifo n – n – 1 pickup
cleanup unix n – n – 0 cleanup
qmgr fifo n – n – 1 qmgr
#qmgr fifo n – n – 1 nqmgr
#tlsmgr fifo – – n – 1 tlsmgr
rewrite unix – – n – – trivial-rewrite
bounce unix – – n – 0 bounce
defer unix – – n – 0 bounce
trace unix – – n – 0 bounce
verify unix – – n – 1 verify
flush unix n – n – 0 flush
proxymap unix – – n – – proxymap
smtp unix – – n – – smtp
relay unix – – n – – smtp
# -o smtp_helo_timeout=5 -o smtp_connect_timeout=5
showq unix n – n – – showq
error unix – – n – – error
local unix – n n – – local
virtual unix – n n – – virtual
lmtp unix – – n – – lmtp
anvil unix – – n – 1 anvil
465 inet n – n – – smtpd
#
# Interfaces to non-Postfix software. Be sure to examine the manual
# pages of the non-Postfix software to find out what options it wants.
#
# maildrop. See the Postfix MAILDROP_README file for details.
#
maildrop unix – n n – – pipe
flags=DRhu user=vmail argv=/usr/local/bin/maildrop -d ${recipient}
#
# The Cyrus deliver program has changed incompatibly, multiple times.
#
old-cyrus unix – n n – – pipe
flags=R user=cyrusimap argv=/cyrus/bin/deliver -e -m ${extension} ${user}
# Cyrus 2.1.5 (Amos Gouaux)
# Also specify in main.cf: cyrus_destination_recipient_limit=1
cyrus unix – n n – 10 pipe
user=cyrusimap argv=/usr/bin/cyrus/bin/deliver -e -r ${sender} -m ${extension} ${user}
uucp unix – n n – – pipe
flags=Fqhu user=uucp argv=uux -r -n -z -a$sender – $nexthop!rmail ($recipient)
ifmail unix – n n – – pipe
flags=F user=ftn argv=/usr/lib/ifmail/ifmail -r $nexthop ($recipient)
bsmtp unix – n n – – pipe
flags=Fq. user=foo argv=/usr/local/sbin/bsmtp -f $sender $nexthop $recipient

As you can see I have it set to relay out 465 but it doesnt want to work Any ideas?